[1] Caroline Wozniacki (DEN) bye
[Q] Greta Arn (HUN) - [Q] Laura Robson (GBR)
Kateryna Bondarenko (UKR) - Anabel Medina Garrigues (ESP)
Dominika Cibulkova (SVK) - [16] Anastasia Pavlyuchenkova (RUS)
[10] Svetlana Kuznetsova (RUS) - Agnes Szavay (HUN)
Gisela Dulko (ARG) - Andrea Petkovic (GER)
Olga Govortsova (BLR) - [Q] Iveta Benesova (CZE)
[6] Agnieszka Radwanska (POL) bye
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[4] Samantha Stosur (AUS) bye
Julia Goerges (GER) - Dinara Safina (RUS)
[Q] Coco Vandeweghe (USA) - Klara Zakopalova (CZE)
Polona Hercog (SLO) - [14] Aravane Rezai (FRA)
[11] Marion Bartoli (FRA) - Yanina Wickmayer (BEL)
Alisa Kleybanova (RUS) - Ana Ivanovic (SRB)
[Q] 張凱貞 (TPE) - Lucie Safarova (CZE)
[8] Victoria Azarenka (BLR) bye
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[5] Francesca Schiavone (ITA) bye
Alexandra Dulgheru (ROU) - [Q] Ekaterina Makarova (RUS)
Angelique Kerber (GER) - Daniela Hantuchova (SVK)
[WC] 伊達公子 (JPN) - [12] Maria Sharapova (RUS)
[13] Shahar Peer (ISR) - Timea Bacsinszky (SUI)
Melanie Oudin (USA) - Kaia Kanepi (EST)
Petra Kvitova (CZE) - Alona Bondarenko (UKR)
[3] Jelena Jankovic (SRB) bye
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[7] Elena Dementieva (RUS) bye
Yaroslava Shvedova (KAZ) - [WC] 奈良Kurumi (JPN)
[Q] Christina Mchale (USA) - Flavia Pennetta (ITA)
Maria Kirilenko (RUS) - [9] 李娜 (CHN)
[15] Nadia Petrova (RUS) - [Q] Roberta Vinci (ITA)
[WC] 森田Ayumi (JPN) - Tsvetana Pironkova (BUL)
Barbora Zahlavova Strycova (CZE) - Sara Errani (ITA)
[2] Vera Zvonareva (RUS) bye
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